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2.2 Atomic Theory

CHEMISTRY 2e
Chapter 2 - Atoms, Molecules and Ions
Evolution of Atomic Theory (2.2)


. . . was a British physicist that discovered the first subatomic particle, the electron, in 1897. observed that the beam in a gas discharge tube was affected by a magnetic field - it was deflected by the negative pole and attracted to the positive pole. From his initial observations and subsequent detailed measurements, Thomson concluded that . . . .

Activity: click the green button on the power supply to create a flow of electrons in the Cathode Ray Tube. Click/drag the positively charged electric plate to deflect the beam of electrons (negatively charged subatomic particles).
  1. The beam (and particles making up the beam) are negatively charged.
  2. The particles have significantly less mass than atoms.
  3. The particles are the "same" regardless of the source material.

Thomson calculated the charge-to-mass ratio of the particle as 1.759 × 1011 Coulombs/kg. While Thomson is credited with the discovery of the electron, the physicist George Stoney was the first to use the name "electron".

Activity:: complete the Lab 2.1: Gas Discharge Tubes And The Discovery Of The Electron lab.




. . . was an American experimental physicist that determined the charge of an electron and an accurate value of Planck's constant. determined the charge of an electron with his famous Video of Millikan's Experiment In the experiment, a microscopic oil droplet with an electron on its surface was suspended in air with an applied electric field. From the experimental data, Millikan calculated the charge of an electron (1.5924 × 10-19 C). Dividing the charge (in Coulombs) by Thomson's charge-to-mass ratio (1.759 × 1011 Coulombs/kg) gave the mass of the electron as 9.053 × 10-31 kg (the accepted value is 9.107 × 10-31 kg).


. . . was a New Zealand experimental physicist that investigated the structure of the atom and the chemistry of radioactive elements. aimed a beam of . . . the nucleus of a Helium atom. It contains 2 protons and 2 neutrons. It has a +2 charge and a mass of 4 amu. at a thin piece of gold foil in what is known as the Video of Rutherford's Experiment Rutherford made a remarkable observation - a small percentage of the particles were deflected from their straight-line path and an even smaller number bounced back toward the source. Rutherford concluded that . . . .

  1. Most of the atom's volume is empty space.
  2. A positively-charged nucleus caused the deflections.
  3. In rare instances, a small, relatively heavy nucleus was struck by the much lighter alpha particle causing it to bounce backwards.
  4. Rutherford discovered the proton.

How did Rutherford know Thomson had previously discovered the negatively charged electron, so there must be a positively charged particle to make the overall charge of an atom equal zero. In addition, the path of a positively-charged α particle will be altered (deflected) by a positively-charged nucleus ("like charges repel").



The Atomic Summary

Thomson discovered the  electron  when he deflected "cathode rays" with a charged plate.
Millikan calculated the charge of an  electron  on an "oil drop".
Rutherford discovered that the nucleus contained densely-packed positive particles ( protons ). It turns out that the nucleus contains another densely-packed particle . . . . mouseover the red nucleus to see this other particle.